(1)证明:由题意,A(3,0,0),D(0,-3,0),M(1,0,2),N(0,1,0),则 MN =(-1,1,-2), AD =(-3,-3,0).∴ MN ? AD =3-3+0=0,∴ MN ⊥ AD ,∴MN⊥AD;(2)解:∵P(0,0,3),A(3,0,0),D(0,-3,0),∴ PA =(3,0,-3), AD =(-3,-3,0),设平面PAD的法向量为